Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
نویسندگان
چکیده
In the title complex, [Cu(C(13)H(11)N(3)O(2))(2)(C(12)H(8)N(2))](NO(3))(2), the Cu(II )atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the Cu(II)atom by a pyridine N atom. These four atoms form a slightly distorted square-planar N(4) donor set. In the packing, two additional Cu⋯O inter-actions occur [Cu⋯O = 2.462 (2) Å], resulting in a typical Jahn-Teller-distorted octahedral environment around the Cu atom. N-H⋯O hydrogen bonds result in a three-dimensional network. The O atoms of the anion are disordered over two positions in a 0.68 (2):0.32 (2) ratio.
منابع مشابه
Two novel bis(2,9-dimethyl-1,10-phenanthroline)copper(I) complexes: [Cu(dmp)2]2(PF6)2.0.5(bpmh).CH3CN and [Cu(dmp)2][N(CN)2].
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In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa-hedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu-phen units in zigzag chains extending parallel to [100]. Inter-chain C-H⋯O hyd...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010